In Situ Synthesis of an Imidazolate‐4‐amide‐5‐imidate Ligand and Formation of a Microporous Zinc–Organic Framework with H 2 ‐and CO 2 ‐Storage Ability | Zendy

Debatin Franziska | Zendy; Thomas Arne | Zendy; Kelling Alexandra | Zendy; Hedin Niklas | Zendy; Bacsik Zoltan | Zendy; Senkovska Irena | Zendy; Kaskel Stefan | Zendy; Junginger Matthias | Zendy; Müller Holger | Zendy; Schilde Uwe | Zendy; Jäger Christian | Zendy; Friedrich Alwin | Zendy; Holdt HansJürgen | Zendy

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In Situ Synthesis of an Imidazolate‐4‐amide‐5‐imidate Ligand and Formation of a Microporous Zinc–Organic Framework with H 2 ‐and CO 2 ‐Storage Ability

Author(s) -

Debatin Franziska,

Thomas Arne,

Kelling Alexandra,

Hedin Niklas,

Bacsik Zoltan,

Senkovska Irena,

Kaskel Stefan,

Junginger Matthias,

Müller Holger,

Schilde Uwe,

Jäger Christian,

Friedrich Alwin,

Holdt HansJürgen

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200906188

Subject(s) - microporous material , zinc , amide , imidazolate , chemistry , ligand (biochemistry) , in situ , chelation , hydrolysis , metal organic framework , polymer chemistry , inorganic chemistry , organic chemistry , receptor , biochemistry , adsorption

Narrow channels with polar walls are the structural and functional features responsible for the high capacity of a zinc–organic framework based on an imidazolate–amide–imidate ligand for the uptake of H 2 and CO 2 (see structure: orange Zn, blue N, red O, dark gray C, light gray H). The rigid and stable chelating ligand was synthesized in situ by partial hydrolysis of a dicyanoimidazole compound.

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