A Diatomic Molecule Receptor That Removes CO in a Living Organism | Zendy

Kitagishi Hiroaki | Zendy; Negi Shigeru | Zendy; Kiriyama Akiko | Zendy; Honbo Akino | Zendy; Sugiura Yukio | Zendy; Kawaguchi Akira T. | Zendy; Kano Koji | Zendy

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A Diatomic Molecule Receptor That Removes CO in a Living Organism

Author(s) -

Kitagishi Hiroaki,

Negi Shigeru,

Kiriyama Akiko,

Honbo Akino,

Sugiura Yukio,

Kawaguchi Akira T.,

Kano Koji

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200906149

Subject(s) - porphyrin , organism , chemistry , receptor , ligand (biochemistry) , supramolecular chemistry , cyclodextrin , molecule , biophysics , stereochemistry , biochemistry , biology , organic chemistry , genetics

A CO stripper : The O 2 ‐bound form of an iron(II) porphyrin cyclodextrin supramolecular complex (hemoCD) infused into a rat vein reacted with internal CO through ligand exchange, and the CO‐bound hemoCD was immediately excreted in the urine (see picture). The hemoCD acting as a CO receptor made it possible to quantify endogenous CO in a living organism.

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