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Ruthenium Bis(σ‐BH) Aminoborane Complexes from Dehydrogenation of Amine–Boranes: Trapping of H 2 BNH 2
Author(s) -
Alcaraz Gilles,
Vendier Laure,
Clot Eric,
SaboEtienne Sylviane
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200905970
Subject(s) - boranes , ruthenium , dehydrogenation , chemistry , trapping , amine gas treating , photochemistry , organic chemistry , catalysis , boron , ecology , biology
One small step for ammonia–borane : The simplest elementary aminoborane compound H 2 BNH 2 , which results from dehydrogenation of ammonia–borane, has been trapped by a ruthenium complex fragment leading to the isolation of a bis(σ‐BH) aminoborane complex. The analogous H 2 BNHMe and H 2 BNMe 2 complexes were also prepared. (Picture: ruthenium complex; Ru purple, P orange, N blue, B brown, H white.)