Ruthenium Bis(σ‐BH) Aminoborane Complexes from Dehydrogenation of Amine–Boranes: Trapping of H 2 BNH 2 | Zendy

Alcaraz Gilles | Zendy; Vendier Laure | Zendy; Clot Eric | Zendy; SaboEtienne Sylviane | Zendy

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Ruthenium Bis(σ‐BH) Aminoborane Complexes from Dehydrogenation of Amine–Boranes: Trapping of H 2 BNH 2

Author(s) -

Alcaraz Gilles,

Vendier Laure,

Clot Eric,

SaboEtienne Sylviane

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200905970

Subject(s) - dehydrogenation , chemistry , ammonia borane , ruthenium , boranes , borane , medicinal chemistry , transition metal , photochemistry , catalysis , organic chemistry , boron

One small step for ammonia–borane : The simplest elementary aminoborane compound H 2 BNH 2 , which results from dehydrogenation of ammonia–borane, has been trapped by a ruthenium complex fragment leading to the isolation of a bis(σ‐BH) aminoborane complex. The analogous H 2 BNHMe and H 2 BNMe 2 complexes were also prepared. (Picture: ruthenium complex; Ru purple, P orange, N blue, B brown, H white.)

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