A Molecular Double Ball Bearing: An Ag I –Pt II  Dodecanuclear Quadruple‐Decker Complex with Three Rotors | Zendy

Hiraoka Shuichi | Zendy; Hisanaga Yoshihiro | Zendy; Shiro Motoo | Zendy; Shionoya Mitsuhiko | Zendy

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A Molecular Double Ball Bearing: An Ag I –Pt II Dodecanuclear Quadruple‐Decker Complex with Three Rotors

Author(s) -

Hiraoka Shuichi,

Hisanaga Yoshihiro,

Shiro Motoo,

Shionoya Mitsuhiko

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200905947

Subject(s) - ball (mathematics) , bridging (networking) , crystallography , molecular machine , ion , physics , chemistry , stereochemistry , computer science , materials science , mathematics , nanotechnology , geometry , quantum mechanics , computer network

A marvelous machine : A 2.5 nm sized molecular machine that behaves like a double ball bearing with three rotors was constructed from two kinds of disk‐shaped ligands, Ag I ions, and dinuclear Pt II bridging complexes (see structure: C red, N blue, O purple, S green, Ag yellow, Pt brown). Motion of the three rotors was found to depend greatly on the degree of interlocking between the two ligands in rotor 2 through helix inversion.

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