Selective Oxidative Cleavage of Cp* from Coordinated GaCp*: Naked Ga +  in [GaNi(GaCp*) 4 ] +  and [(μ 2 ‐Ga)  n  M 3 (GaCp*) 6 ]  n + | Zendy

Halbherr Markus | Zendy; Bollermann Timo | Zendy; Gemel Christian | Zendy; Fischer Roland A. | Zendy

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Selective Oxidative Cleavage of Cp* from Coordinated GaCp*: Naked Ga + in [GaNi(GaCp*) 4 ] + and [(μ 2 ‐Ga) n M 3 (GaCp*) 6 ] n +

Author(s) -

Halbherr Markus,

Bollermann Timo,

Gemel Christian,

Fischer Roland A.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200905920

Subject(s) - chemistry , crystallography , intermetallic , cleavage (geology) , stereochemistry , oxidative cleavage , transition metal , molecule , materials science , organic chemistry , catalysis , fracture (geology) , composite material , alloy

The naked and the edge : The selective oxidative cleavage of Cp* from coordinated GaCp* ligands lead to the cluster cations [(μ 2 ‐Ga) 2 Pd 3 (GaCp*) 6 ] 2+ and [(μ 2 ‐Ga)Pt 3 (GaCp*) 6 ] + (see structure) which are the first examples of the edge‐bridging coordination mode of “naked” Ga + . This chemistry is a step towards a rational synthesis of metal‐rich molecules as discrete models for intermetallic phases.

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