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Experimental Detection and Properties of H 2 O⋅⋅⋅AgCl and H 2 S⋅⋅⋅AgCl by Rotational Spectroscopy
Author(s) -
Harris Stephanie J.,
Legon Anthony C.,
Walker Nicholas R.,
Wheatley David E.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200905799
Subject(s) - spectroscopy , analytical chemistry (journal) , materials science , chemistry , physics , crystallography , quantum mechanics , chromatography
Silver service : Two simple compounds, H 2 O⋅⋅⋅AgCl and H 2 S⋅⋅⋅AgCl (see picture), formed by interaction of either H 2 O or H 2 S with AgCl, are detected by rotational spectroscopy. AgCl is produced by laser ablation of silver in the presence of CCl 4 and then picks up H 2 O or H 2 S. H 2 O⋅⋅⋅AgCl is isomorphic with its hydrogen‐ and halogen‐bonded analogues H 2 O⋅⋅⋅HCl and H 2 O⋅⋅⋅ClF, while H 2 S⋅⋅⋅AgCl is similarly related to H 2 S⋅⋅⋅HCl and H 2 S⋅⋅⋅ClF.