Experimental Detection and Properties of H 2 O⋅⋅⋅AgCl and H 2 S⋅⋅⋅AgCl by Rotational Spectroscopy | Zendy

Harris Stephanie J. | Zendy; Legon Anthony C. | Zendy; Walker Nicholas R. | Zendy; Wheatley David E. | Zendy

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Experimental Detection and Properties of H 2 O⋅⋅⋅AgCl and H 2 S⋅⋅⋅AgCl by Rotational Spectroscopy

Author(s) -

Harris Stephanie J.,

Legon Anthony C.,

Walker Nicholas R.,

Wheatley David E.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200905799

Subject(s) - spectroscopy , analytical chemistry (journal) , materials science , chemistry , physics , crystallography , quantum mechanics , chromatography

Silver service : Two simple compounds, H 2 O⋅⋅⋅AgCl and H 2 S⋅⋅⋅AgCl (see picture), formed by interaction of either H 2 O or H 2 S with AgCl, are detected by rotational spectroscopy. AgCl is produced by laser ablation of silver in the presence of CCl 4 and then picks up H 2 O or H 2 S. H 2 O⋅⋅⋅AgCl is isomorphic with its hydrogen‐ and halogen‐bonded analogues H 2 O⋅⋅⋅HCl and H 2 O⋅⋅⋅ClF, while H 2 S⋅⋅⋅AgCl is similarly related to H 2 S⋅⋅⋅HCl and H 2 S⋅⋅⋅ClF.

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