Premium
A Dynamically Inverting π‐Bowl Complex
Author(s) -
Amaya Toru,
Wang WenZhen,
Sakane Hiroyuki,
Moriuchi Toshiyuki,
Hirao Toshikazu
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200905567
Subject(s) - inversion (geology) , solvent , chemistry , geology , chemical physics , organic chemistry , paleontology , structural basin
The super bowl : The dynamic inversion behaviour of [CpRu(η 6 ‐sumanene)]PF 6 (see picture; sumanene=C 21 H 12 ) was investigated in solution by NMR studies. This result, the first elucidation of bowl‐to‐bowl inversion in π‐bowl transition metal complexes, is solvent‐ and temperature‐dependent.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom