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A Dynamically Inverting π‐Bowl Complex
Author(s) -
Amaya Toru,
Wang WenZhen,
Sakane Hiroyuki,
Moriuchi Toshiyuki,
Hirao Toshikazu
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200905567
Subject(s) - inversion (geology) , solvent , chemistry , geology , chemical physics , organic chemistry , paleontology , structural basin
The super bowl : The dynamic inversion behaviour of [CpRu(η 6 ‐sumanene)]PF 6 (see picture; sumanene=C 21 H 12 ) was investigated in solution by NMR studies. This result, the first elucidation of bowl‐to‐bowl inversion in π‐bowl transition metal complexes, is solvent‐ and temperature‐dependent.