Polyoxometalates Made of Gold: The Polyoxoaurate [Au III  4 As V  4 O 20 ] 8− | Zendy

Izarova Natalya V. | Zendy; Vankova Nina | Zendy; Heine Thomas | Zendy; Biboum Rosa Ngo | Zendy; Keita Bineta | Zendy; Nadjo Louis | Zendy; Kortz Ulrich | Zendy

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Polyoxometalates Made of Gold: The Polyoxoaurate [Au III 4 As V 4 O 20 ] 8−

Author(s) -

Izarova Natalya V.,

Vankova Nina,

Heine Thomas,

Biboum Rosa Ngo,

Keita Bineta,

Nadjo Louis,

Kortz Ulrich

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200905566

Subject(s) - chemistry , ion , crystallography , arsenate , inorganic chemistry , organic chemistry , arsenic

More noble than ever : The first fully inorganic discrete polynuclear gold(III) oxo complex [Au III 4 As V 4 O 20 ] 8− (see structure; Au yellow, As blue, O red) was prepared by condensation of [Au(OH) 4 ] − in the presence of AsO 4 3− ions under mild reaction conditions. The resulting polyoxoaurate exhibits a tetrameric structure with square‐planar coordinated Au III ions linked by oxo and arsenate bridging ligands.

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