Palladium‐Catalyzed Intramolecular Carboesterification of Olefins | Zendy

Li Yang | Zendy; Jardine Katherine J. | Zendy; Tan Runyu | Zendy; Song Datong | Zendy; Dong Vy M. | Zendy

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Palladium‐Catalyzed Intramolecular Carboesterification of Olefins

Author(s) -

Li Yang,

Jardine Katherine J.,

Tan Runyu,

Song Datong,

Dong Vy M.

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200905478

Subject(s) - intramolecular force , vicinal , palladium , olefin fiber , catalysis , chemistry , ring (chemistry) , cycloaddition , surface modification , cascade , cascade reaction , medicinal chemistry , organic chemistry , chromatography

One catalyst, three bonds : The title reaction between propiolic acids and unactivated olefins (see scheme; O red, Cl green) results in vicinal functionalization of the olefin, with the formation of new CC and CO bonds. Structurally complex 6,7,5‐tricyclic ring systems are formed in a single step by this cascade chloropalladation and formal [3+2] cycloaddition.

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