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Strong Two‐Photon Excited Fluorescence and Stimulated Emission from an Organic Single Crystal of an Oligo(Phenylene Vinylene)
Author(s) -
Gao Fei,
Liao Qing,
Xu ZhenZhen,
Yue YongHao,
Wang Qiang,
Zhang HaoLi,
Fu HongBing
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200905428
Subject(s) - materials science , fluorescence , phenylene , quantum yield , photon upconversion , excited state , lasing threshold , optoelectronics , single crystal , photochemistry , absorption (acoustics) , fluorescence anisotropy , photon , photonics , photoluminescence , optics , luminescence , atomic physics , crystallography , polymer , chemistry , physics , wavelength , composite material
Low in, high out : Single crystals of a thiomethyl‐terminated oligo(phenylene vinylene) exhibit unique photonic properties including strong anisotropic solid‐state fluorescence (see depicted optical and fluorescence micrographs; arrows: polarization direction), high quantum yield, large two‐photon absorption cross section, and stimulated emission, which make it a candidate for opto‐electronic applications such as upconversion lasing.

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