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Arylimidovanadium(V) Complexes for a Tridendritic Centrosymmetric Structural Motif or Axial Chirality
Author(s) -
Moriuchi Toshiyuki,
Nishina Masafumi,
Hirao Toshikazu
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200905425
Subject(s) - chirality (physics) , motif (music) , structural motif , crystallography , chemistry , stereochemistry , physics , chiral symmetry , biochemistry , quantum mechanics , nambu–jona lasinio model , quark , acoustics
For V′s a jolly good fellow : A one‐pot reaction of aniline derivatives with VO(O i Pr) 3 in the presence of NaH affords either trinuclear arylimidovanadium(V) triisopropoxide with a tridendritic centrosymmetric structure (see picture, left) or axially chiral binuclear arylimidovanadium(V) triisopropoxide (right), wherein self‐assembly creates a highly ordered molecular arrangement in the solid state.