Arylimidovanadium(V) Complexes for a Tridendritic Centrosymmetric Structural Motif or Axial Chirality | Zendy

Moriuchi Toshiyuki | Zendy; Nishina Masafumi | Zendy; Hirao Toshikazu | Zendy

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Arylimidovanadium(V) Complexes for a Tridendritic Centrosymmetric Structural Motif or Axial Chirality

Author(s) -

Moriuchi Toshiyuki,

Nishina Masafumi,

Hirao Toshikazu

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200905425

Subject(s) - chirality (physics) , motif (music) , structural motif , crystallography , chemistry , stereochemistry , physics , chiral symmetry , biochemistry , quantum mechanics , nambu–jona lasinio model , quark , acoustics

For V′s a jolly good fellow : A one‐pot reaction of aniline derivatives with VO(O i Pr) 3 in the presence of NaH affords either trinuclear arylimidovanadium(V) triisopropoxide with a tridendritic centrosymmetric structure (see picture, left) or axially chiral binuclear arylimidovanadium(V) triisopropoxide (right), wherein self‐assembly creates a highly ordered molecular arrangement in the solid state.

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