Palladium‐Catalyzed Coupling Reactions of Thioimidate N‐Oxides: Access to α‐Alkenyl‐ and α‐Aryl‐Functionalized Cyclic Nitrones | Zendy

Schleiss Julie | Zendy; Rollin Patrick | Zendy; Tatibouët Arnaud | Zendy

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Palladium‐Catalyzed Coupling Reactions of Thioimidate N‐Oxides: Access to α‐Alkenyl‐ and α‐Aryl‐Functionalized Cyclic Nitrones

Author(s) -

Schleiss Julie,

Rollin Patrick,

Tatibouët Arnaud

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200905188

Subject(s) - aryl , palladium , scope (computer science) , catalysis , combinatorial chemistry , function (biology) , chemistry , coupling reaction , scheme (mathematics) , computer science , organic chemistry , mathematics , programming language , alkyl , mathematical analysis , evolutionary biology , biology

Surprisingly useful are thioimidate N‐oxides in the preparation of aryl‐ and vinyl‐substituted cyclic ketonitrones through the Liebeskind–Srogl reaction. This novel synthetic approach appears to be efficient and have a broad scope (see scheme).

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