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Wacker‐Type Oxidation of Internal Olefins Using a PdCl 2 / N , N ‐Dimethylacetamide Catalyst System under Copper‐Free Reaction Conditions
Author(s) -
Mitsudome Takato,
Mizumoto Keiichi,
Mizugaki Tomoo,
Jitsukawa Koichiro,
Kaneda Kiyotomi
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200905184
Subject(s) - dimethylacetamide , catalysis , copper , wacker process , chemistry , solvent , organic chemistry , palladium
A simple catalyst system consisting of PdCl 2 and N , N ‐dimethylacetamide (DMA) as the solvent can successfully promote Wacker‐type oxidation of internal olefins. This catalyst system does not require copper compounds and is tolerant of a wide range of substrates having internal olefins.
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