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Highly Enantioselective Hydrophosphonylation of Aldehydes: Base‐Enhanced Aluminum–salalen Catalysis
Author(s) -
Suyama Keitaro,
Sakai Yoshifumi,
Matsumoto Kazuhiro,
Saito Bunnai,
Katsuki Tsutomu
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200905158
Subject(s) - phosphonate , enantioselective synthesis , conjugated system , base (topology) , chemistry , aluminium , catalysis , computer science , organic chemistry , information retrieval , combinatorial chemistry , mathematics , mathematical analysis , polymer
The dimethyl phosphonate hydrophosphonylation of conjugated‐ and non‐conjugated aldehydes into their corresponding α‐hydroxy phosphonates was achieved using chiral aluminum–salalen complex 1 (see scheme).
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