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A Unique Pd 4 Platform with CH 3 and μ‐CH 2 Groups and Its CC Coupling Reaction with Simple Olefins
Author(s) -
Sachse Anna,
John Michael,
Meyer Franc
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200904745
Subject(s) - bridging (networking) , ethylene , simple (philosophy) , propene , computer science , chemistry , information retrieval , organic chemistry , catalysis , philosophy , computer network , epistemology
Ménage à quatre : The Pd 4 complex 1 features both terminal CH 3 and bridging CH 2 groups, and it reacts with ethylene at room temperature to give mainly propene. NMR spectroscopic studies reveal several intermediates in the formation of 1 from Pd 2 building blocks.