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Linear Trimer of Diruthenium Linked by Butadiyn‐Diyl Units: A Unique Electronic Wire
Author(s) -
Ying JieWen,
Liu Isiah PoChun,
Xi Bin,
Song You,
Campana Charles,
Zuo JingLin,
Ren Tong
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200904674
Ru communicating? Butadiyn‐diyl bridges link three Ru 2 moieties together to give a molecular wire (see structure, red Ru, green C, blue N, purple O). Voltammetric, spectroscopic, and magnetic data all point to extensive electronic delocalization across the linear trimer.