Efficient and Selective Room‐Temperature Gold‐Catalyzed Reduction of Nitro Compounds with CO and H 2 O as the Hydrogen Source | Zendy

He Lin | Zendy; Wang LuCun | Zendy; Sun Hao | Zendy; Ni Ji | Zendy; Cao Yong | Zendy; He HeYong | Zendy; Fan KangNian | Zendy

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Efficient and Selective Room‐Temperature Gold‐Catalyzed Reduction of Nitro Compounds with CO and H 2 O as the Hydrogen Source

Author(s) -

He Lin,

Wang LuCun,

Sun Hao,

Ni Ji,

Cao Yong,

He HeYong,

Fan KangNian

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200904647

Subject(s) - chemoselectivity , nitro , catalysis , yield (engineering) , chemistry , environmentally friendly , hydrogen , combinatorial chemistry , inorganic chemistry , organic chemistry , materials science , metallurgy , ecology , alkyl , biology

Taking hydrogen from water : Gold catalysis enabled the selective reduction of nitro compounds under very mild conditions with a combination of H 2 O and CO as the reductant (see scheme). This environmentally friendly reaction proceeded in high yield and with high chemoselectivity in the presence of a wide range of functional groups.

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