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Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area
Author(s) -
Ben Teng,
Ren Hao,
Ma Shengqian,
Cao Dapeng,
Lan Jianhui,
Jing Xiaofei,
Wang Wenchuan,
Xu Jun,
Deng Feng,
Simmons Jason M.,
Qiu Shilun,
Zhu Guangshan
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200904637
Subject(s) - benzene , toluene , porosity , surface (topology) , porous medium , diamond , carbon fibers , chemical engineering , specific surface area , chemistry , hydrogen bond , computer science , materials science , organic chemistry , molecule , mathematics , engineering , composite material , catalysis , composite number , geometry
Diamonds are forever : A diamond‐like framework in which the C–C bonds are replaced with rigid phenyl rings (see picture) is not only structurally stable but also has a large internal surface area. This porous aromatic framework (PAF‐1) demonstrates high uptake capacities of hydrogen and carbon dioxide as well as benzene and toluene vapors, and has an unprecedented surface area of 7100 m 2 g −1 .