Electron‐Transfer Properties of an Efficient Nonheme Iron Oxidation Catalyst with a Tetradentate Bispidine Ligand | Zendy

Comba Peter | Zendy; Fukuzumi Shunichi | Zendy; Kotani Hiroaki | Zendy; Wunderlich Steffen | Zendy

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Electron‐Transfer Properties of an Efficient Nonheme Iron Oxidation Catalyst with a Tetradentate Bispidine Ligand

Author(s) -

Comba Peter,

Fukuzumi Shunichi,

Kotani Hiroaki,

Wunderlich Steffen

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200904427

Subject(s) - catalysis , dissociation (chemistry) , electron transfer , chemistry , ligand (biochemistry) , kinetics , bond dissociation energy , electron , redox , photochemistry , inorganic chemistry , organic chemistry , receptor , physics , quantum mechanics , biochemistry

The oxidation catalyst [(L)Fe IV O] (see picture; L is a tetradentate bispidine ligand) has the highest known one‐electron reduction potential for a Fe IV O species (0.73 V vs. SCE). Investigations into the electron‐transfer kinetics show a linear correlation with the bond dissociation energy of the organic substrates.

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