Crystal Structures of C 94 (CF 3 ) 20  and C 96 (C 2 F 5 ) 12  Reveal the Cage Connectivities in C 94  (61) and C 96  (145) Fullerenes | Zendy

Tamm Nadezhda B. | Zendy; Sidorov Lev N. | Zendy; Kemnitz Erhard | Zendy; Troyanov Sergey I. | Zendy

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Crystal Structures of C 94 (CF 3 ) 20 and C 96 (C 2 F 5 ) 12 Reveal the Cage Connectivities in C 94 (61) and C 96 (145) Fullerenes

Author(s) -

Tamm Nadezhda B.,

Sidorov Lev N.,

Kemnitz Erhard,

Troyanov Sergey I.

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200904331

Subject(s) - fullerene , crystal structure , crystallography , crystal (programming language) , chemistry , physics , organic chemistry , computer science , programming language

Perfluoroalkylation of a mixture of higher fullerenes has yielded the first direct proof of the cage connectivities in C 94 (isomer 61) and C 96 (isomer 145). The addition patterns of the R F groups on these fullerene cages, the largest to be structurally investigated to date, were determined by X‐ray structure analyses of C 94 (CF 3 ) 20 (see structure; gray C, green F) and C 96 (C 2 F 5 ) 12 .

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