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Organotrifluoroborates and Monocoordinated Palladium Complexes as Catalysts—A Perfect Combination for Suzuki–Miyaura Coupling
Author(s) -
Molander Gary A.,
Canturk Belgin
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200904306
Subject(s) - palladium , steric effects , chemistry , catalysis , coupling reaction , combinatorial chemistry , coupling (piping) , suzuki reaction , organic chemistry , materials science , metallurgy
Monocoordinated palladium catalysts derived from sterically hindered, electron‐rich phosphines or N‐heterocyclic carbenes have revolutionized the Suzuki–Miyaura coupling reaction. The emergence of organotrifluoroborates has provided important new perspectives for the organoboron component of these reactions. In combination, these two components prove to be extraordinarily powerful partners for cross‐coupling reactions.