Reaction Control in Synthetic Organic Photochemistry: Switching between [5+2] and [2+2] Modes of Cycloaddition | Zendy

Roscini Claudio | Zendy; Cubbage Kara L. | Zendy; Berry Malcolm | Zendy; OrrEwing Andrew J. | Zendy; BookerMilburn Kevin I. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Reaction Control in Synthetic Organic Photochemistry: Switching between [5+2] and [2+2] Modes of Cycloaddition

Author(s) -

Roscini Claudio,

Cubbage Kara L.,

Berry Malcolm,

OrrEwing Andrew J.,

BookerMilburn Kevin I.

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200904059

Subject(s) - cycloaddition , mode (computer interface) , control (management) , computer science , irradiation , scheme (mathematics) , chemistry , information retrieval , organic chemistry , artificial intelligence , physics , mathematics , human–computer interaction , nuclear physics , mathematical analysis , catalysis

Split personality : Reaction conditions that enable powerful control over the mode of photocycloaddition in maleimides have been developed. Direct irradiation favors the [5+2] mode whereas sensitized irradiation allows a complete switch to the [2+2] mode (see scheme; TBS= tert ‐butyldimethylsilyl).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research