Soluble Molecular Dimers of CaO and SrO Stabilized by a Lewis Acid | Zendy

Sarish Sankaranarayana Pillai | Zendy; Nembenna Sharanappa | Zendy; Roesky Herbert W. | Zendy; Ott Holger | Zendy; Pal Aritra | Zendy; Stalke Dietmar | Zendy; Dutta Sudipta | Zendy; Pati Swapan K. | Zendy

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Soluble Molecular Dimers of CaO and SrO Stabilized by a Lewis Acid

Author(s) -

Sarish Sankaranarayana Pillai,

Nembenna Sharanappa,

Roesky Herbert W.,

Ott Holger,

Pal Aritra,

Stalke Dietmar,

Dutta Sudipta,

Pati Swapan K.

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200904054

Subject(s) - deprotonation , alkaline earth metal , chemistry , hydroxide , metal , earth (classical element) , medicinal chemistry , inorganic chemistry , organic chemistry , mathematics , ion , mathematical physics

Soluble oxides : The reaction between a β‐diketiminate aluminum methyl hydroxide and [M{N(SiMe 3 ) 2 } 2 (thf) 2 ] (M=Ca, Sr) results in alkaline‐earth‐metal oxides such as [{LAl(Me)(μ‐O)Ca(thf)} 2 ] (see core structure; L is deprotonated β‐diketiminate CH{C(CH 2 )}(CMe)(2,6‐ i Pr 2 C 6 H 3 N) 2 ). These soluble complexes are dimeric in the solid state and contain unprecedented M 2 O 2 cores.

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