Tunable, Temperature‐Responsive Polynorbornenes with Side Chains Based on an Elastin Peptide Sequence | Zendy

Conrad Rosemary M. | Zendy; Grubbs Robert H. | Zendy

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Tunable, Temperature‐Responsive Polynorbornenes with Side Chains Based on an Elastin Peptide Sequence

Author(s) -

Conrad Rosemary M.,

Grubbs Robert H.

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200903888

Subject(s) - lower critical solution temperature , monomer , metathesis , copolymer , norbornene , polymerization , chemistry , polymer chemistry , sequence (biology) , peptide , side chain , polymer , pyridine , combinatorial chemistry , organic chemistry , biochemistry

Live on : Random copolymers made by living ring‐opening metathesis polymerization of norbornene monomers containing either the elastin peptide sequence ‐(VPGVG)‐ or pentaethylene glycol (see scheme; Mes=mesityl, pyr=pyridine) exhibit a lower critical solution temperature (LCST). The LCST can be easily modified by varying the ratio of the co‐monomers in the polymer feed.

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