Supramolecular Catalyst for Aldehyde Hydrogenation and Tandem Hydroformylation–Hydrogenation | Zendy

Diab Lisa | Zendy; Šmejkal Tomáš | Zendy; Geier Jens | Zendy; Breit Bernhard | Zendy

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Supramolecular Catalyst for Aldehyde Hydrogenation and Tandem Hydroformylation–Hydrogenation

Author(s) -

Diab Lisa,

Šmejkal Tomáš,

Geier Jens,

Breit Bernhard

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200903620

Subject(s) - hydroformylation , bifunctional , aldehyde , catalysis , tandem , supramolecular chemistry , chemistry , ligand (biochemistry) , chemoselectivity , combinatorial chemistry , substrate (aquarium) , organic chemistry , molecule , rhodium , materials science , biochemistry , receptor , oceanography , composite material , geology

The chemoselective reduction of aldehydes and the tandem hydroformylation–hydrogenation of terminal alkenes are possible with a supramolecular catalyst that operates by a novel mechanism involving substrate activation by hydrogen bonding and subsequent metal–ligand bifunctional hydrogenation (see scheme).

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