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Trifluoromethanesulfanylamides as Easy‐to‐Handle Equivalents of the Trifluoromethanesulfanyl Cation (CF 3 S + ): Reaction with Alkenes and Alkynes
Author(s) -
Ferry Aurélien,
Billard Thierry,
Langlois Bernard R.,
Bacqué Eric
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200903387
Subject(s) - reagent , electrophile , toluene , chemistry , organic chemistry , sulfonyl , electrophilic addition , medicinal chemistry , unit (ring theory) , combinatorial chemistry , catalysis , mathematics , mathematics education , alkyl
Making introductions : The CF 3 S unit can be added in an electrophilic fashion to alkenes and alkynes in reactions with trifluoromethanesulfanylamide reagents (see scheme; Ts=toluene‐4‐sulfonyl). The products obtained may be of interest, for example, in pharmaceutical chemistry and materials science.