Premium
A Gadolinium‐Bridged Polytungstoarsenate(III) Nanocluster: [Gd 8 As 12 W 124 O 432 (H 2 O) 22 ] 60−
Author(s) -
Hussain Firasat,
Conrad Franziska,
Patzke Greta R.
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200903299
Subject(s) - polyoxometalate , gadolinium , nanochemistry , tungsten , crystallography , chemistry , nanotechnology , materials science , organic chemistry , catalysis
POMs de terre : The combination of tungsten‐containing polyoxometalate (POM) fragments with gadolinium cations results in exceptionally long polyoxotungstates. The title anion (see structure; W green, As purple, Gd blue, O red, H 2 O cyan) is almost 5 nm in length, resulting in a challenging solution chemistry and also new perspectives for POMs in nanochemistry.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom