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Rhodium‐Catalyzed Cross‐Coupling of Organoboron Compounds with Vinyl Acetate
Author(s) -
Yu JungYi,
Kuwano Ryoichi
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200903146
Subject(s) - rhodium , catalysis , chemistry , organoboron compounds , palladium , nickel , organic chemistry , carbon fibers , coupling reaction , vinyl acetate , coupling (piping) , medicinal chemistry , combinatorial chemistry , polymer chemistry , composite number , materials science , copolymer , polymer , composite material , metallurgy
A new coupling partner : Vinyl acetate couples with organoboron compounds in the presence of a rhodium catalyst; carbon–carbon bond formation occurs on the vinylic carbon attached to the acetoxy group. Conventional nickel and palladium catalysts were found to be ineffective for the reaction.