Rhodium‐Catalyzed Cross‐Coupling of Organoboron Compounds with Vinyl Acetate | Zendy

Yu JungYi | Zendy; Kuwano Ryoichi | Zendy

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Rhodium‐Catalyzed Cross‐Coupling of Organoboron Compounds with Vinyl Acetate

Author(s) -

Yu JungYi,

Kuwano Ryoichi

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200903146

Subject(s) - rhodium , catalysis , chemistry , organoboron compounds , palladium , nickel , organic chemistry , carbon fibers , coupling reaction , vinyl acetate , coupling (piping) , medicinal chemistry , combinatorial chemistry , polymer chemistry , composite number , materials science , copolymer , polymer , composite material , metallurgy

A new coupling partner : Vinyl acetate couples with organoboron compounds in the presence of a rhodium catalyst; carbon–carbon bond formation occurs on the vinylic carbon attached to the acetoxy group. Conventional nickel and palladium catalysts were found to be ineffective for the reaction.

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