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Fast Ion‐Transfer Processes at Nanoscopic Liquid/Liquid Interfaces
Author(s) -
Li Qing,
Xie Shubao,
Liang Zhongwei,
Meng Xin,
Liu Shujuan,
Girault Hubert H.,
Shao Yuanhua
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200903143
Subject(s) - interface (matter) , computer science , mass transfer , ion , electrochemistry , voltammetry , nanoscopic scale , transfer (computing) , cyclic voltammetry , liquid liquid , information transfer , nanotechnology , analytical chemistry (journal) , chemistry , materials science , electrode , environmental chemistry , chromatography , organic chemistry , telecommunications , bubble , maximum bubble pressure method , parallel computing
Keeping up : The fastest kinetic data for ion transfer at a liquid/liquid interface were evaluated by nanopipette voltammetry. The steady‐state voltammograms can be explained by theoretical models. In previous electrochemical measurements the systematic underestimation of k 0 is probably a result of inefficient mass transfer to the relatively large interface.