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Adsorption and Catalytic Properties of the Inner Nanospace of a Gigantic Ring‐Shaped Polyoxometalate Cluster
Author(s) -
Noro Shinichiro,
Tsunashima Ryo,
Kamiya Yuichi,
Uemura Kazuhiro,
Kita Hidetoshi,
Cronin Leroy,
Akutagawa Tomoyuki,
Nakamura Takayoshi
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200903142
Subject(s) - polyoxometalate , adsorption , cluster (spacecraft) , catalysis , ring (chemistry) , chemistry , materials science , nanotechnology , computer science , organic chemistry , computer network
Functional inner space : A gigantic ring‐shaped {Mo 154 } polyoxometalate cluster anion can be stabilized by encapsulation in dimethyldioctadecylammonium (DODA) cations. Its inner nanospace enables adsorption of gases and vapors, and it acts as a water‐tolerant solid acid catalyst (see scheme).