Adsorption and Catalytic Properties of the Inner Nanospace of a Gigantic Ring‐Shaped Polyoxometalate Cluster | Zendy

Noro Shinichiro | Zendy; Tsunashima Ryo | Zendy; Kamiya Yuichi | Zendy; Uemura Kazuhiro | Zendy; Kita Hidetoshi | Zendy; Cronin Leroy | Zendy; Akutagawa Tomoyuki | Zendy; Nakamura Takayoshi | Zendy

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Adsorption and Catalytic Properties of the Inner Nanospace of a Gigantic Ring‐Shaped Polyoxometalate Cluster

Author(s) -

Noro Shinichiro,

Tsunashima Ryo,

Kamiya Yuichi,

Uemura Kazuhiro,

Kita Hidetoshi,

Cronin Leroy,

Akutagawa Tomoyuki,

Nakamura Takayoshi

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200903142

Subject(s) - polyoxometalate , adsorption , cluster (spacecraft) , catalysis , ring (chemistry) , chemistry , materials science , nanotechnology , computer science , organic chemistry , computer network

Functional inner space : A gigantic ring‐shaped {Mo 154 } polyoxometalate cluster anion can be stabilized by encapsulation in dimethyldioctadecylammonium (DODA) cations. Its inner nanospace enables adsorption of gases and vapors, and it acts as a water‐tolerant solid acid catalyst (see scheme).

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