A Series of Mixed‐Metal Borohydrides | Zendy

Ravnsbæk Dorthe | Zendy; Filinchuk Yaroslav | Zendy; Cerenius Yngve | Zendy; Jakobsen Hans J. | Zendy; Besenbacher Flemming | Zendy; Skibsted Jørgen | Zendy; Jensen Torben R. | Zendy

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A Series of Mixed‐Metal Borohydrides

Author(s) -

Ravnsbæk Dorthe,

Filinchuk Yaroslav,

Cerenius Yngve,

Jakobsen Hans J.,

Besenbacher Flemming,

Skibsted Jørgen,

Jensen Torben R.

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200903030

Subject(s) - borohydride , zinc , alkali metal , series (stratigraphy) , metal , crystallography , chemistry , inorganic chemistry , materials science , organic chemistry , geology , paleontology , catalysis

Mix and match : A novel series of alkali‐metal zinc borohydrides, LiZn 2 (BH 4 ) 5 (see picture), NaZn 2 (BH 4 ) 5 , and NaZn(BH 4 ) 3 , with fascinating structures are presented. An interpenetrated network structure, containing a [Zn 2 (BH 4 ) 5 ] − ion, is observed for the first time for a borohydride. A three‐dimensional framework containing a polymeric [{Zn(BH 4 ) 3 } n ] n − ion is also identified.

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