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Molybdenum(0)‐Promoted Carbonylative Cyclization of o ‐Haloaryl‐ and β‐Haloalkenylimine Derivatives by Oxidative Addition of a Carbon(sp 2 )Halogen Bond: Preparation of Two Types of γ‐Lactams
Author(s) -
Takaya Jun,
Sangu Kenichiro,
Iwasawa Nobuharu
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200902884
Subject(s) - halogen , molybdenum , transformation (genetics) , chemistry , combinatorial chemistry , organic chemistry , gene , biochemistry , alkyl
Lovely lactams : Synthetically useful γ‐lactam derivatives have been prepared through the unique title transformation. By utilizing the characteristic property of the molybdenum complex, two kinds of products (both of which have rarely been obtained by reactions catalyzed by late transition metals) were obtained selectively by adjusting the reaction conditions (see scheme).