Modulating Electronic Interactions between Closely Spaced Complementary π Surfaces with Different Outcomes: Regio‐ and Diastereomerically Pure Subphthalocyanine–C 60  Tris Adducts | Zendy

GonzálezRodríguez David | Zendy; Carbonell Esther | Zendy; Guldi Dirk M. | Zendy; Torres Tomás | Zendy

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Modulating Electronic Interactions between Closely Spaced Complementary π Surfaces with Different Outcomes: Regio‐ and Diastereomerically Pure Subphthalocyanine–C 60 Tris Adducts

Author(s) -

GonzálezRodríguez David,

Carbonell Esther,

Guldi Dirk M.,

Torres Tomás

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200902767

Subject(s) - adduct , tris , chemistry , computational chemistry , photochemistry , organic chemistry , biochemistry

Tightly coupled , regio‐ and diastereomerically pure subphthalocyanine–C 60 dyads (see space‐filling depiction; B orange, C light blue, H gray, N blue, O red), tethered by means of a tris‐addition reaction, can follow different mechanisms on photoexcitation (electron transfer or energy transfer), depending on the spacing between the two complementary π surfaces.

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