Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole | Zendy

Wang Tongdao | Zendy; Li Shunhua | Zendy; Zhang Hong | Zendy; Lin Ran | Zendy; Han Feifei | Zendy; Lin Yumei | Zendy; Wen Ting Bin | Zendy; Xia Haiping | Zendy

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Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole

Author(s) -

Wang Tongdao,

Li Shunhua,

Zhang Hong,

Lin Ran,

Han Feifei,

Lin Yumei,

Wen Ting Bin,

Xia Haiping

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200902738

Subject(s) - annulation , scheme (mathematics) , computer science , intramolecular force , information retrieval , nucleophilic aromatic substitution , library science , world wide web , chemistry , mathematics , stereochemistry , medicinal chemistry , nucleophilic substitution , organic chemistry , mathematical analysis , catalysis

Fused metallaaromatics have been conveniently prepared from metallabenzenes (see scheme). The intramolecular S N Ar reaction of an osmabenzene allowed the first examples of a metallabenzothiazole and a metallabenzoxazole to be isolated.

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