Transformation of Ethylzinc Species to Zinc Acetate Mediated by O 2  Activation: Reactive Oxygen‐Centered Radicals Under Control | Zendy

Lewiński Janusz | Zendy; Kościelski Marek | Zendy; Suwała Karolina | Zendy; Justyniak Iwona | Zendy

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Transformation of Ethylzinc Species to Zinc Acetate Mediated by O 2 Activation: Reactive Oxygen‐Centered Radicals Under Control

Author(s) -

Lewiński Janusz,

Kościelski Marek,

Suwała Karolina,

Justyniak Iwona

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200902716

Subject(s) - zinc , radical , chemistry , transformation (genetics) , reactive oxygen species , redox , oxygen , combinatorial chemistry , medicinal chemistry , organic chemistry , biochemistry , gene

The controlled oxygenation of ethylzinc complexed with a tridentate pyrroloimine leads to an unprecedented transformation of the resulting ethylperoxide into an acetate. The zinc acetate appears to form without involvement of redox‐active metal centers by a combination of OO bond activation and multiple rearrangements of ZnO . and . OEt radical species.

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