Size‐Selective Sorption of Small Organic Molecules in One‐Dimensional Channels of an Ionic Crystalline Organic–Inorganic Hybrid Compound Stabilized by π–π Interactions | Zendy

Tagami Hanae | Zendy; Uchida Sayaka | Zendy; Mizuno Noritaka | Zendy

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Size‐Selective Sorption of Small Organic Molecules in One‐Dimensional Channels of an Ionic Crystalline Organic–Inorganic Hybrid Compound Stabilized by π–π Interactions

Author(s) -

Tagami Hanae,

Uchida Sayaka,

Mizuno Noritaka

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200902681

Subject(s) - sorption , ionic bonding , butane , propane , molecule , crystal (programming language) , organic molecules , materials science , organic compound , ionic compound , chemistry , chemical engineering , ion , organic chemistry , adsorption , computer science , engineering , programming language , catalysis

Very selective : The cross‐sectional area of the narrowest channel opening in an organic–inorganic porous ionic crystal that possesses one‐dimensional channels is around 30 Å 2 . The compound sorbs molecules such as propane, 1‐propanol, and 1,2‐dichloroethane, which have cross‐sectional areas smaller than the channel opening, while n ‐butane, 1‐butanol, and 1,2‐dichloropropane are excluded (see picture).

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