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Dehydrogenative Dimerization of Di‐ tert ‐butyltin Dihydride Photochemically and Thermally Catalyzed by Iron and Molybdenum Complexes
Author(s) -
Sharma Hemant K.,
AriasUgarte Renzo,
MettaMagana Alejandro J.,
Pannell Keith H.
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200902327
Subject(s) - molybdenum , tin , catalysis , yield (engineering) , chemistry , photochemistry , materials science , organic chemistry , metallurgy
Tin–tin bonds are formed in the title reaction, which provides t Bu 2 HSnSnH t Bu 2 in high yield. The reaction is either photochemically catalyzed by the iron complex [(η 5 ‐C 5 H 5 )Fe(CO) 2 Me] or its molybdenum analogue [(η 5 ‐C 5 H 5 )Mo(CO) 3 Me] or thermally catalyzed by [(η 5 ‐C 5 H 5 )Fe(CO)(PPh 3 )Me] or its analogue [(η 5 ‐C 5 H 5 )Mo(CO) 2 (PPh 3 )Me].