Dehydrogenative Dimerization of Di‐ tert ‐butyltin Dihydride Photochemically and Thermally Catalyzed by Iron and Molybdenum Complexes | Zendy

Sharma Hemant K. | Zendy; AriasUgarte Renzo | Zendy; MettaMagana Alejandro J. | Zendy; Pannell Keith H. | Zendy

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Dehydrogenative Dimerization of Di‐ tert ‐butyltin Dihydride Photochemically and Thermally Catalyzed by Iron and Molybdenum Complexes

Author(s) -

Sharma Hemant K.,

AriasUgarte Renzo,

MettaMagana Alejandro J.,

Pannell Keith H.

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200902327

Subject(s) - molybdenum , tin , catalysis , yield (engineering) , chemistry , photochemistry , materials science , organic chemistry , metallurgy

Tin–tin bonds are formed in the title reaction, which provides t Bu 2 HSnSnH t Bu 2 in high yield. The reaction is either photochemically catalyzed by the iron complex [(η 5 ‐C 5 H 5 )Fe(CO) 2 Me] or its molybdenum analogue [(η 5 ‐C 5 H 5 )Mo(CO) 3 Me] or thermally catalyzed by [(η 5 ‐C 5 H 5 )Fe(CO)(PPh 3 )Me] or its analogue [(η 5 ‐C 5 H 5 )Mo(CO) 2 (PPh 3 )Me].

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