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Structural Characterization of a Base‐Stabilized [Zn 2 ] 2+ Cation
Author(s) -
Schulz Stephan,
Schuchmann Daniella,
Krossing Ingo,
Himmel Daniel,
Bläser Dieter,
Boese Roland
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200902202
Subject(s) - dication , zinc , chemistry , base (topology) , zinc compounds , characterization (materials science) , nuclear chemistry , ion , materials science , organic chemistry , nanotechnology , mathematics , mathematical analysis
Something to zinc about : A base‐stabilized [Zn 2 ] 2+ dication, obtained from the reaction of [Cp* 2 Zn 2 (dmap) 2 ] (Cp*=C 5 Me 5 , dmap=4‐dimethylaminopyridine) with two equivalents of [H(OEt 2 ) 2 ][Al{OC(CF 3 ) 3 } 4 ], is structurally characterized for the first time (see structure; red Zn, blue N, gray C; ZnZn 2.419(1) Å).