Structural Characterization of a Base‐Stabilized [Zn 2 ] 2+  Cation | Zendy

Schulz Stephan | Zendy; Schuchmann Daniella | Zendy; Krossing Ingo | Zendy; Himmel Daniel | Zendy; Bläser Dieter | Zendy; Boese Roland | Zendy

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Structural Characterization of a Base‐Stabilized [Zn 2 ] 2+ Cation

Author(s) -

Schulz Stephan,

Schuchmann Daniella,

Krossing Ingo,

Himmel Daniel,

Bläser Dieter,

Boese Roland

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200902202

Subject(s) - dication , zinc , chemistry , base (topology) , zinc compounds , characterization (materials science) , nuclear chemistry , ion , materials science , organic chemistry , nanotechnology , mathematics , mathematical analysis

Something to zinc about : A base‐stabilized [Zn 2 ] 2+ dication, obtained from the reaction of [Cp* 2 Zn 2 (dmap) 2 ] (Cp*=C 5 Me 5 , dmap=4‐dimethylaminopyridine) with two equivalents of [H(OEt 2 ) 2 ][Al{OC(CF 3 ) 3 } 4 ], is structurally characterized for the first time (see structure; red Zn, blue N, gray C; ZnZn 2.419(1) Å).

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