Hypervalent Carbon Atom: “Freezing” the S N 2 Transition State | Zendy

Pierrefixe Simon C. A. H. | Zendy; van Stralen Sebastiaan J. M. | Zendy; van Stralen Joost N. P. | Zendy; Fonseca Guerra Célia | Zendy; Bickelhaupt F. Matthias | Zendy

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Hypervalent Carbon Atom: “Freezing” the S N 2 Transition State

Author(s) -

Pierrefixe Simon C. A. H.,

van Stralen Sebastiaan J. M.,

van Stralen Joost N. P.,

Fonseca Guerra Célia,

Bickelhaupt F. Matthias

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200902125

Subject(s) - hypervalent molecule , atom (system on chip) , carbon fibers , state (computer science) , chemistry , carbon atom , transition (genetics) , crystallography , stereochemistry , computer science , organic chemistry , programming language , operating system , algorithm , alkyl , reagent , composite number , biochemistry , gene

High Five! Under certain circumstances a carbon atom can become hypervalent (see structure) and bind five substituents in the trigonal‐bipyramidal structure, which is normally the labile S N 2 transition state.

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