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Transition‐Metal‐Catalyzed Ring Opening of Hetero‐Diels–Alder Adducts
Author(s) -
Hilt Gerhard
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200901939
Subject(s) - heteroatom , adduct , ring (chemistry) , bicyclic molecule , catalysis , transition metal , chemistry , diels–alder reaction , stereochemistry , organic chemistry
Either–or: Exciting developments have been made in the field of transition‐metal‐catalyzed ring‐opening reactions of bicyclic, heteroatom‐containing Diels–Alder adducts. These regio‐ und stereodivergent reactions open interesting new alternatives to conventional methods (see scheme, cod=1,5‐cyclooctadiene).