Enantioselective Linchpin Catalysis by SOMO Catalysis: An Approach to the Asymmetric α‐Chlorination of Aldehydes and Terminal Epoxide Formation | Zendy

Amatore Muriel | Zendy; Beeson Teresa D. | Zendy; Brown Sean P. | Zendy; MacMillan David W. C. | Zendy

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Enantioselective Linchpin Catalysis by SOMO Catalysis: An Approach to the Asymmetric α‐Chlorination of Aldehydes and Terminal Epoxide Formation

Author(s) -

Amatore Muriel,

Beeson Teresa D.,

Brown Sean P.,

MacMillan David W. C.

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200901855

Subject(s) - enantioselective synthesis , epoxide , catalysis , terminal (telecommunication) , chemistry , transformation (genetics) , combinatorial chemistry , stereochemistry , organic chemistry , computer science , biochemistry , telecommunications , gene

Time for SOme MOre : For the first time SOMO (singly occupied molecular orbital) activation has been exploited to allow a new approach to the α‐chlorination of aldehydes. This transformation can be readily implemented as part of a linchpin catalysis approach to the enantioselective production of terminal epoxides.

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