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Bis(allyl)calcium
Author(s) -
Jochmann Phillip,
Dols Thomas S.,
Spaniol Thomas P.,
Perrin Lionel,
Maron Laurent,
Okuda Jun
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200901743
Subject(s) - calcium , chemistry , computer science , organic chemistry
Bis(allyl)calcium is surprisingly stable and has good solubility in THF. The compound crystallizes as a triglyme adduct (see picture; C gray, O red). Selective CC coupling to give 1,5‐hexadiene is observed upon reaction with iodine.