Premium
Practical Synthesis of the Dendralene Family Reveals Alternation in Behavior
Author(s) -
Payne Alan D.,
Bojase Gomotsang,
PaddonRow Michael N.,
Sherburn Michael S.
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200901733
Subject(s) - alternation (linguistics) , psychology , linguistics , philosophy
Back from obscurity : The practical synthesis of the first six members of the fundamental class of acyclic branched oligoalkenes has been achieved. The syntheses allow access to the target compounds on multigram scales in good yields. Members of the family with even numbers of double bonds are significantly more stable than those with odd numbers (see picture), and exhibit different chemical reactivities in Diels–Alder reactions.