Poly(polyoxotungstate)s with 20 Nickel Centers: From Nanoclusters to One‐Dimensional Chains | Zendy

Zheng ShouTian | Zendy; Zhang Jie | Zendy; ClementeJuan Juan Modesto | Zendy; Yuan DaQiang | Zendy; Yang GuoYu | Zendy

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Poly(polyoxotungstate)s with 20 Nickel Centers: From Nanoclusters to One‐Dimensional Chains

Author(s) -

Zheng ShouTian,

Zhang Jie,

ClementeJuan Juan Modesto,

Yuan DaQiang,

Yang GuoYu

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200901653

Subject(s) - nanoclusters , nickel , chemistry , materials science , polymer chemistry , crystallography , metallurgy , nanotechnology

Line them up : Under hydrothermal conditions, trilacunary Keggin { B‐α ‐PW 9 O 34 } fragments and nickel ions form the two largest Ni‐substituted poly(polyoxotungstate)s with the greatest number of Ni ions in a known polyoxometalate. Bridging amine ligands connect the fragments to form the 1D structure of the polyoxometalates (see structure; red octahedra WO 6 , yellow tetrahedra PO 4 , green Ni, red O, blue N, gray C).

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