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Low‐Coordinate Boride Ligands: A True Trimetalloborane
Author(s) -
Braunschweig Holger,
Dewhurst Rian D.,
Kraft Katharina,
Radacki Krzysztof
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200901211
Subject(s) - manganese , boron , atom (system on chip) , cobalt , boride , bridging (networking) , chemistry , planar , crystallography , stereochemistry , inorganic chemistry , computer science , organic chemistry , computer graphics (images) , computer network , embedded system
Boron trifecta : The first true trimetalloborane has been synthesized by simple salt elimination from a dimanganese bromoborylene and Na[Co(CO) 4 ]. The complex was structurally characterized, and features only first‐row transition metals, a planar boron atom, and two semi‐bridging CO ligands between the cobalt and one manganese atom (see picture).