Direct CC Cross‐Coupling of Secondary and Primary Alcohols Catalyzed by a γ‐Alumina‐Supported Silver Subnanocluster | Zendy

Shimizu Kenichi | Zendy; Sato Ryosuke | Zendy; Satsuma Atsushi | Zendy

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Direct CC Cross‐Coupling of Secondary and Primary Alcohols Catalyzed by a γ‐Alumina‐Supported Silver Subnanocluster

Author(s) -

Shimizu Kenichi,

Sato Ryosuke,

Satsuma Atsushi

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200901057

Subject(s) - primary (astronomy) , catalysis , coupling (piping) , coupling reaction , materials science , chemistry , organic chemistry , composite material , physics , astronomy

Let's drink to that! Two alcohols (one primary and one secondary) can be coupled in an atom‐efficient process by a hydrogen‐autotransfer catalytic system in the form of silver subnanoclusters supported on γ‐Al 2 O 3 . The recyclable heterogeneous catalyst promoted the one‐pot CC cross‐coupling in the presence of a catalytic amount of the weak base Cs 2 CO 3 (see reaction mechanism).

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