Adapting N‐Heterocyclic Carbene/Azide Coupling Chemistry for Polymer Synthesis: Enabling Access to Aromatic Polytriazenes | Zendy

Coady Daniel J. | Zendy; Khramov Dimitri M. | Zendy; Norris Brent C. | Zendy; Tennyson Andrew G. | Zendy; Bielawski Christopher W. | Zendy

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Adapting N‐Heterocyclic Carbene/Azide Coupling Chemistry for Polymer Synthesis: Enabling Access to Aromatic Polytriazenes

Author(s) -

Coady Daniel J.,

Khramov Dimitri M.,

Norris Brent C.,

Tennyson Andrew G.,

Bielawski Christopher W.

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200901046

Subject(s) - carbene , azide , fluorene , conjugated system , polymer , chemistry , click chemistry , luminescence , photochemistry , coupling (piping) , combinatorial chemistry , polymer chemistry , materials science , organic chemistry , catalysis , optoelectronics , metallurgy

A click by any other name : Coupling bis(N‐heterocyclic carbene)s with bis(azide)s afforded a novel class of conjugated polytriazenes. These polymers were rendered electrically conductive upon doping, and fluorene‐containing variants exhibited luminescence. This adaptation of N‐heterocyclic carbene (NHC)/azide coupling chemistry to polymer synthesis reveals the potential of NHCs as building blocks for accessing polymers having useful electronic properties.

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