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All Kinds of Reactivity: Recent Breakthroughs in Metal‐Catalyzed Alkyne Chemistry
Author(s) -
Anaya de Parrodi Cecilia,
Walsh Patrick J.
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200900900
Subject(s) - alkyne , reactivity (psychology) , bifunctional , chemistry , catalysis , combinatorial chemistry , organic chemistry , medicine , alternative medicine , pathology
Alkynes of reactions : Recent breakthroughs in metal‐catalyzed alkyne reactions, which expand the synthetic utility of alkynes, have been achieved. These approaches broaden the range of alkynes that are accessible by CN and CC bond‐forming reactions and demonstrate that the use of bifunctional heterobimetallic catalysts can lead to new reactivity and excellent enantioselectivity (see scheme).