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A Hydride‐Rich Magnesium Cluster
Author(s) -
Arrowsmith Merle,
Hill Michael S.,
MacDougall Dugald J.,
Mahon Mary F.
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200900878
Subject(s) - magnesium hydride , magnesium , phenylsilane , adduct , hydride , cluster (spacecraft) , chemistry , molecule , medicinal chemistry , hydrogen , organic chemistry , catalysis , computer science , programming language
High‐de‐hydride! A straightforward reaction between a magnesium silylamido/N‐heterocyclic carbene adduct and phenylsilane provides a {Mg 4 H 6 } cluster molecule that may be regarded as a combination of two magnesium dihydride and two magnesium monohydride moieties.