Perfluoropentaphenylborole: A New Approach to Lewis Acidic, Electron‐Deficient Compounds | Zendy

Huynh Keith | Zendy; Vignolle Joan | Zendy; Tilley T. Don | Zendy

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Perfluoropentaphenylborole: A New Approach to Lewis Acidic, Electron‐Deficient Compounds

Author(s) -

Huynh Keith,

Vignolle Joan,

Tilley T. Don

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200900695

Subject(s) - lewis acids and bases , catalysis , combinatorial chemistry , chemistry , electron , coupling (piping) , field (mathematics) , nanotechnology , materials science , organic chemistry , physics , mathematics , metallurgy , pure mathematics , quantum mechanics

Zirconocene is the key : A new synthetic method, which utilizes zirconocene‐mediated coupling of alkynes, has been developed for the preparation of a new class of highly Lewis acidic boroles (see scheme). Such compounds hold potential for applications in catalysis and the field of electron‐deficient organic materials.

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